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MATERIAL SAFETY DATA SHEET
SIG Manufacturing Company
Ph:800-247-5008
65 Bradrock Rd
Des Plaines, IL 60018
CHEMTREC Emergency Telephone number: 800-424-9300
Issue date: January 1, 2010
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SECTION 1 - PRODUCT IDENTIFICATION
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Chemical Name: Modified Butyrate Solution
Trade Name: Sig Supercoat Color Dope
Chemical Family: Lacquer/Varnish

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SECTION 2 - HAZARDOUS INGREDIENTS
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Ingredients CAS % Exposure limits

Ethyl Acetate 99 141-78-6 25 400 PPM
 
Butyl Acetate 123-86-4 15 100 PPM

SDA-3A 64-17-5 5 1000 PPM

Toluol 108-88-3 20 100 PPM

MEK 78-93-3 10 200 PPM

Diacetone Alcohol 123-42-2 10 50 PPM
 
NOTE: Exposure limits are listed in TLV/PEL/STEL.

NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.

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SECTION 3 - PHYSICAL DATA
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Boiling Point: 165øF
Per Cent Volatile: 85% by weight
Evap. Rate: N/A
Vapor Pressure: N/A
Vapor Density: Heavier than air
Specific Gravity: 0.915
Solubility in Water: Insoluble
Appearance and Odor: Clear to slight haze; solvent odor

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SECTION 4 - FIRE AND EXPLOSION HAZARD DATA
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Flash Point: 21øF TCC
Flammable Limits: L.E.L.: 1.40 U.E.L.: 19.0
Extinguishing Media: Extinguish fires with carbon dioxide, water fog, steam, or Dry chemical. Cool fire-exposed metal containers with water spray.
Special Fire Fighting Procedures: Cool down material after blaze is struck.
Unusual Fire and Explosion Hazards: When exposed to heat and flame, the material is a fire and explosion hazard. When this material is involved in a fire, toxic degradation products can be produced, including carbon dioxide, carbon monoxide, and oxides of nitrogen. Firefighters should use self-contained breathing apparatus. Dense toxic smoke can be produced when this material burns. Flammability Class: N/A
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SECTION 5 - HEALTH HAZARD DATA
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Effects of Overexposure: Prolonged or repeated exposure by inhalation of vapor concentrations or by skin contact with the liquid may cause damage to the nervous system, blood, and kidneys. Symptoms include headache, lethargy, drowsiness, weakness, difficulty walking, personality change, poor appetite, nausea, and weight loss. Vapor irritating to the eyes, nose and throat. Liquid irritating to the eyes.
Emergency First Aid Procedures:
INHALATION–Move to fresh air; if not breathing, give artificial respiration. If breathing is difficult, give oxygen.
INGESTIONDO NOT INDUCE VOMITING. MATERIAL CONTAINS HYDROCARBON BASED SOLVENTS.
EYE OR SKIN CONTACT–Immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention.

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SECTION 6 - REACTIVITY DATA
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Stability: Unstable { } Stable {X}
Hazardous Polymerization: May Occur { } Will Not Occur {X}
Incompatibility: Avoid contamination with strong oxidizing agents, strong acids, strong bases, certain amines. Do not allow film to come in contact with driers unless under agitation.
Conditions to Avoid: Heat, sparks, sources of ignition, and open flames.
Hazardous Decomposition Products: Combustion can produce carbon dioxide and/or carbon monoxide. Dense toxic smoke can be produced when this material burns.

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SECTION 7 - SPILL OR LEAK PROCEDURES
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Steps To Be Taken in Case Material Is Released or Spilled: Eliminate all sources of ignition and keep hot metal surfaces isolated from spill. Flush spilled material into suitable retaining areas or containers with large quantities of water. Small amounts of spilled material may be absorbed into appropriate absorbent
Waste Disposal Method: Dispose of used product and absorbent in compliance with applicable Federal, State and local regulations regarding health and environment. Hazardous liquids may not be disposed of in landfills and will require incineration

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SECTION 8 - SPECIAL PROTECTION INFORMATION
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Respiratory Protection: The use of respiratory protection depends on vapor concentration above the time-weighed TLV; use of a NIOSH approved cartridge respirator or gas mask. General mechanical ventilation may be sufficient to keep product vapor concentrations within specified time-weighted ranges. Other special precautions such as respiratory masks and supplemental local exhaust may be required.
Other Protective Equipment: Chemically inert gloves, aprons, and safety goggles or face shields should be worn at all times. Eye washes and safety showers are recommended in the work area.

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SECTION 9 - SPECIAL PRECAUTIONS
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Precautions To Be Taken In Handling And Storage: Keep product and containers cool, dry and away from any sources of ignition. Use and store this product with adequate ventilation. Keep containers closed when not in use.
Other Precautions: Avoid inhalation of vapors and personal contact with product. Should contact be made, remove saturated clothing and flush affected areas with water. Clean up material that has dried by using non-sparking tools or washing with solvent.

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SECTION 10 - SUPPLEMENTAL INFORMATION
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SARA STATUS: The products, Toluol and Methyl Ethyl Ketone listed in Section II of this MSDS are toxic chemicals according to Section 313 of SARA and are subject to the reporting requirements of 40 CFR Part 372.45
DOT PROPER SHIPPING NAME: Paint
UN NUMBER: UN 1263
DOT HAZARD CLASS: FLAMMABLE LIQUID
NFPA HAZARD CODE: HEALTH 2; FLAMMABILITY 3; REACTIVITY 0

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This information is furnished without warranty, representation, inducement or license of any kind, except that it is accurate to the best of Sig Manufacturing Company, Inc's. knowledge, or obtained from sources believed by Sig Manufacturing Company, Inc. to be accurate, and Sig Manufacturing Company, Inc. does not assume any legal responsibility for its use or reliance upon the same. Customers are encouraged to conduct their own tests. Before using any product, read its label.

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